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Why oils smoke and break down

Intermediate Kitchen science

Every fat starts to break apart and smoke at some temperature, and how refined and fresh the oil is changes that point.

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How do you do it?

  1. Use refined oils like canola, peanut, avocado or vegetable oil for searing and frying above about 400°F.
  2. Save unrefined oils like extra-virgin olive, unrefined sesame and butter for gentler cooking or finishing, where their flavor shines.
  3. Store oils sealed in a cool, dark cupboard and smell them before using; rancid oil smells like crayons or old paint.
  4. Strain frying oil after use and discard it once it darkens, smells off or smokes at normal frying heat.

Why does it work?

Cooking oils are mostly fat molecules called triglycerides. Strong heat, oxygen and water break them into free fatty acids and glycerol, and glycerol breaks down further into acrolein, the acrid smoke that stings your eyes. Unrefined oils hold bits of fruit, seed and free fatty acids that burn sooner, so they smoke lower than refined oils of the same kind. Every use breaks down more fat, so reused frying oil smokes at lower temperatures, tastes harsh and darkens. Smoke point is a rough guide, not a precise number; it varies by brand and batch, and some oils resist oxidation better than their smoke point suggests.

What are the common mistakes?

Still stuck? Watch someone do it on YouTube.

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